Effect of Eu3+-doping on morphology and fluorescent properties of neodymium vanadate nanorod-arrays

Tetragonal structural (t-NdVO₄) nanorod-arrays were fabricated by simple one-pot hydrothermal method. The phase, morphology and microstructure of NdVO₄ were characterized by X-ray diffractometer, scanning electron microscope (SEM), transmission electron microscope (TEM), dispersive X-ray spectrometer (EDS) and selected area electron diffraction (SAED) techniques. t-NdVO₄ nanorods are single-crystalline with a length of 100 nm and a diameter of 25 nm, which grow orientally along the direction of (112) crystalline plane and self-assemble to form nanorod-arrays. The results show that Eu³⁺-doping interrupts the formation of NdVO₄ nanorod-arrays, and then leads to the red-shift of the strongest luminescence emission of Nd³⁺ transition from ⁴D_3/2 state to ⁴I_11/2 and decreases its intensity of the fluorescence emission at 400 nm sharply. The research results have some reference values to optimize the photoluminescence performance of rare earth vanadates.     

Effect of water aging on the mechanical properties of flax fiber/bio-based resin composites

Present work investigates the effect of hydrothermal aging of flax fiber-reinforced bio-based epoxy resin laminates on the mechanical and thermomechanical properties of the composites. Three different types of bio-based resins were used. Plates reinforced with eight layers plain weave flax fibers of 150 g/m², manufactured using Resin Transfer Molding (RTM), compression molding or autoclave technique depends on type of the resin. One dimensional Fickian behavior shows a good fitting to the experimental data derived from weight measurements. The water uptake at the equilibrium state in the case of 60 °C temperature was slightly greater than that at 40 °C. The mechanical properties after hydrothermal aging show a significant reduction and do not return to their initial values even after the drying process. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48787.     

Cooperative path planning with priority target assignment and collision avoidance guidance for rescue unmanned surface vehicles in a complex ocean environment

In this paper, a novel cooperative path planning scheme of unmanned surface vehicles (USVs) for rescuing targets in a complex ocean environment is proposed. The primary objective of the rescue USVs is to bring all targets back safely on the premise of first rescuing priority targets, while optimizing the path length, the navigation time and the angular energy. The main contributions of this paper are as follows: (1) The proposed K-means-division (KMD) algorithm is able to identify a complex ocean environment with collision-free zone and static-obstacles zone; (2) The proposed path planning method with fast-marching-method-based ellipse guidance range (E-FMM) is able to optimize the angular energy while ensuring safety; (3) The proposed cooperative management system (including priority-target-assignment (PTA) with reward-mechanism genetic-optimization (RM-GO) and collision-avoidance (CA) guidance law with Tangent-based surge-varying wave-disturbances-observer (Tangent-SV-WDO)) can accomplish the mission of the rescue USVs. Comparative studies with the state-of-the-art methods demonstrate that the proposed cooperative path planning scheme is superior in terms of priority-target-assignment (PTA) and collision-avoidance (CA) of the actual rescue work.     

15层全剪力墙结构居民楼定向爆破拆除

介绍了复杂环境下15层居民楼的定向爆破拆除案例,根据工程特点及周围环境制定了向西南方向倒塌的爆破方案。对1层⁵层非承重墙、楼梯进行局部预拆除;采用重心移出的方法计算爆破高度;计算了楼房的质量,用来确定预留墙体的面积;采用多重闭合电-非电复式起爆网路。通过合理的方案设计和参数选取,取得了良好的爆破效果,塌落振动未对周围建筑产生影响,可为类似工程提供参考。     

基于耦合模型的福州市暴雨内涝研究

以福州市内涝问题为例.通过耦合协调度模型分析了福州市的城市化与水环境耦合关系.并运用综合风险指数评估了福州市内涝风险情况。结果表明.福州市城市化与水环境耦合协调度整体上呈上升趋势,目前已达到优质协调高水平耦合阶段,但城市内涝风险值却不断上升。因此,耦合关系并不能完全表明城市化与水环境的内部矛盾趋势,现阶段仍需注重水环境安全预警能力,预防暴雨内涝的迸发,从而更好地促进城市化与水环境“由外及里,由内而外”的协调发展。     

Structure and properties of bio‐based polyamide 109 treated with superheated water

The structure and properties of bio‐based polyamide 109 (PA109) after treatment with superheated water (140 °C ≤ T ≤ 280 °C) were investigated and characterized by Fourier transform infrared spectroscopy, differential scanning calorimetry, wide‐angle X‐ray diffraction, scanning electron microscopy and small‐angle X‐ray scattering. Below 170 °C, the hydrothermal treatment was considered to be a physical process, which exerted an annealing effect on PA109. It led to an increase in melting temperature, lamellar thickness and crystallinity, while the macromolecular structure, crystal structure and the order of crystalline regions were not affected. Above 170 °C, complete melting/dissolution of PA109 occurred with partial hydrolysis. Due to the high temperature and long reaction time, the hydrolysis reaction became more and more prominent, and the resin was completely hydrolyzed into oligomers at 280 °C. Also, above 170 °C, the hydrothermal treatment was accompanied by a chemical process and the melting temperature and molecular weight decreased progressively. Notably, the crystal structure was not altered, but the degree of perfection of crystals and the order of crystalline regions were broken, especially above 200 °C. The hydrolytic degradation reaction was significantly affected by temperature, while both time and the water to polyamide ratio were secondary factors which influenced it to a minor extent. The process could be considered as a typical nucleophilic substitution reaction which takes place step by step inducing the molecular weight to decrease gradually. Overall, this study provides a ‘green’ route for the processing, recycling and treatment of environmentally friendly polyamides based on hydrothermal treatment technology. © 2019 Society of Chemical Industry     

Does visibility matter? – A simple nudge reduces the purchase of sugar sweetened beverages in canteen drink coolers

Obesity is a growing public health problem and the increased prevalence calls for preventive measures. Choice architecture and dual brain process thinking has been suggested as a promising strategy. One of the behaviors that are of significant public health nutrition concern is the intake of sugar sweetened beverages (SSB’s) of young people. An intervention was developed for 4 canteens for students (age 16–23) of vocational schools. We slightly re-arranged the location of SSB’s in drink coolers by reducing visibility. The canteen managers collected data on sales volumes of beverages in combination over a period of 3 weeks and the data collection was supplemented with interviews and observations. The results showed that the intervention was able to reduce the purchasing of SSB in three of the four canteens. In one of the canteens where the cooler was behind the cafeteria desk there were little difference. It is assumed to be due to the fact that the students could not see the cooler while standing in line. The results suggests that rethinking of the canteen interior and physical food environment has the potential to affect purchasing of SSB.     

Crowdsourcing the perceived urban built environment via social media: The case of underutilized land

Crowdsourcing the public’s perceptions of the built environment in real time enables more responsive and agile infrastructure and land use planning. Social media has emerged to be an effective platform for citizens, engineers, and planners to communicate opinions and feelings transparently. However, a comprehensive terminological resource of the perceived built environment (BE) for consistent data collection and a specified analytical framework are still lacking, particularly for different underutilized land issues. To fill this knowledge gap, we demonstrate a BE-specific term construction and expansion method specifically for collecting Twitter data and propose a Geo-Topic-Sentiment analytical framework for retrieving and analyzing relevant tweets. We conduct a demonstrative study on un(der)utilized land-related BE terms across ten metropolitan statistical areas in the U.S. Findings reveal spatial variations in contents and sentiments about underutilized land environments, and more localized efforts may be required to address specific land use issues across different urban contexts. The research demonstrates Twitter as a useful platform in crowdsourcing perceived BE and sentiments at fine temporal and spatial scales in a timely manner. It contributes to engineering informatics by investigating the role of social media in environmental planning and proposing integrated domain-specific data analytic approaches for engineering practices.     

A test method for evaluating the thermal environment of underground coal mine refuge alternatives

Since 2009, the Mine Safety and Health Administration(MSHA) has required mines to install refuge alternatives(RAs) in underground coal mines. One of the biggest concerns with occupied RAs is the possible severity of the resulting thermal environment. In 30 CFR 7.504, the maximum allowable apparent temperature(AT) for an occupied RA is specified as 35 °C(95 °F). Manufacturers must conduct heat/humidity tests to demonstrate that their RAs meet the 35 °C(95 °F) AT limit. For these tests, heat input devices are used to input the metabolic heat of actual miners. A wide variety of test methods, sensors, and heat input devices could be used when conducting such tests. Since 2012, the National Institute for Occupational Safety and Health(NIOSH) has conducted over thirty 96-hour heat/humidity tests on four different RAs. This paper discusses the test equipment and procedures used during these investigations. This information is useful for RA manufacturers conducting RA heat/humidity tests, for other researchers investigating RA heat/humidity buildup, and for those who need to assess the thermal environment of any confined space where people may be trapped or are seeking refuge.     

Effects of oral administration of timothy hay and psyllium on the growth performance and fecal microbiota of preweaning calves

The objective of this study was to evaluate the effects of oral administration of fiber from the first week of life on the growth and hindgut environment of preweaning calves. Twenty newborn female Holstein calves were divided into 2 groups as control and treatment. Calves in both groups were reared under the same feeding program except for oral fiber administration. Timothy hay and psyllium were mixed at a 50-to-6 ratio as a treatment diet for oral fiber administration. Calves in the treatment group were orally administered 50 g of fiber daily from 3 to 7 d of age and 100 g of fiber from 8 d of age until weaning. Feed intake and occurrence of diarrhea were recorded daily, and body weight (BW) was recorded weekly for the individual calf. Fresh feces were collected from calves at 7, 21, 35, 49, and 56 d of age to analyze fermentation parameters and microbiota to characterize the hindgut environment. Higher fiber intake in the treatment group due to oral administration of timothy and psyllium did not affect the starter intake and achieved higher BW at 21 d of age. The fecal pH, total volatile fatty acid, lactate, and ammonia nitrogen concentrations were not affected by oral fiber administration; meanwhile, the molar proportion of propionate was higher in the treatment group at 7 d of age. The difference in fecal microbiota in the calves subjected to the oral administration of fiber was observed within 21 d of life; Lactobacillus spp. and Prevotella spp. showed higher abundance, whereas that of Clostridium perfringens was decreased. These higher abundances of beneficial bacteria and lower abundance of pathogenic bacteria during early life may partly explain the higher BW of calves in the treatment group at 21 d of age. Furthermore, no adverse effect was observed for the BW and health status in the treatment group throughout the preweaning period. Therefore, early fiber feeding via oral administration potentially contributes to improving the hindgut environment in newborn calves, which leads to better growth of calves during the early stage of life.